Axially Ligated Zirconium(IV) Tetraphenylporphyrin: Synthesis, Characterization, and Biological Activity

Table 2

Optical absorption data of Zr(TPP)(Y)(X) in different solvents.

Compounds	Solvent	(nm), (M^−1 cm^−1)				(cm^−1)
		Zr(TPP)(acac)(phO)	Acetone	413.1	500.5	535.7	579.9		1309.3	1067.2	0.235887
5.074	4.183			4.796	5.009
CH2Cl2	409.4		496.3	532.2	575.8	1241.6	1020.7	0.197404
	5.030		4.126	4.721	4.951
CHCl3	411.3		498.5	533.4	577.5	1278.1	1041.1	0.207468
	5.042		4.139	4.735	4.964
Zr(TPP)(acac)(p-OCH3phO)	Acetone	414.2	501.5	536.8	580.9	1340.2	1085.9	0.252492
		5.101	4.197	4.812	5.031
	CH2Cl2	409.8	496.4	530.6	574.9	1279.9	1039.3	0.207586
		5.057	4.172	4.749	4.965
	CHCl3	411.9	498.3	534.2	578.5	1312.6	1062.4	0.213671
		5.063	4.178	4.765	4.968
Zr(TPP)(acac)(p-CH3phO)	Acetone	412.9	501.4	535.1	580.8	1270.3	1035.2	0.219019
		5.056	4.168	4.788	4.990
	CH2Cl2	409.7	496.3	532.3	576.4	1218.3	992.6	0.183752
		5.002	4.131	4.718	4.932
	CHCl3	411.2	499.1	533.8	577.9	1236.8	1007.9	0.194033
		5.012	4.147	4.729	4.949
Zr(TPP)(acac)(p-NO2phO)	Acetone	410.9	500.2	536.1	582.5	1271.2	1033.2	0.256245
		5.050	4.156	4.728	4.901
	CH2Cl2	408.6	495.2	531.5	576.3	1218.1	991.3	0.191456
		5.010	4.111	4.513	4.899
	CHCl3	410.1	498.9	537.6	577.7	1235.9	1006.7	0.198565
		5.006	4.124	4.279	4.999
Zr(TPP)(acac)(-naphtholate)	Acetone	413.5	500.4	535.2	581.9	1272.3	1034.2	0.232365
		5.045	4.116	4.718	4.912
	CH2Cl2	411.5	497.8	535.6	577.6	1217.3	9956	0.182536
		5.013	4.113	4.518	4.922
	CHCl3	413.5	498.3	535.8	578.9	1235.8	1005.3	0.195632
		5.102	4.127	4.739	4.948