Abstract
The photocatalytic oxidation (PCO) of the steroid estrogens (SEs),
The photocatalytic oxidation (PCO) of the steroid estrogens (SEs),
J. J. Amaral Mendes, “The endocrine disrupters: a major medical challenge,” Food and Chemical Toxicology, vol. 40, no. 6, pp. 781–788, 2002.
View at: Publisher Site | Google ScholarC. Purdom, P. Hardiman, V. Bye, N. Eno, C. Tyler, and J. P. Sumpter, “Estrogenic effects of effluents from sewage treatment works,” Chemistry and Ecology, vol. 8, no. 4, pp. 275–285, 1994.
View at: Google ScholarM. Pettersson, M. Adolfsson-Erici, J. Parkkonen, L. Förlin, and L. Asplund, “Fish bile used to detect estrogenic substances in treated sewage water,” The Science of the Total Environment, vol. 366, no. 1, pp. 174–186, 2006.
View at: Publisher Site | Google ScholarC. Desbrow, E. J. Routledge, G. C. Brighty, J. P. Sumpter, and M. Waldock, “Identification of estrogenic chemicals in STW effluent. 1. Chemical fractionation and in vitro biological screening,” Environmental Science and Technology, vol. 32, no. 11, pp. 1549–1558, 1998.
View at: Publisher Site | Google ScholarA. C. Johnson and J. P. Sumpter, “Removal of endocrine-disrupting chemicals in activated sludge treatment works,” Environmental Science and Technology, vol. 35, no. 24, pp. 4697–4703, 2001.
View at: Publisher Site | Google ScholarG. D'Ascenzo, A. Di Corcia, A. Gentili et al., “Fate of natural estrogen conjugates in municipal sewage transport and treatment facilities,” The Science of the Total Environment, vol. 302, no. 1–3, pp. 199–209, 2003.
View at: Publisher Site | Google ScholarC. Baronti, R. Curini, G. D'Ascenzo, A. Di Corcia, A. Gentili, and R. Samperi, “Monitoring natural and synthetic estrogens at activated sludge sewage treatment plants and in a receiving river water,” Environmental Science and Technology, vol. 34, no. 24, pp. 5059–5066, 2000.
View at: Publisher Site | Google ScholarA. C. Johnson, H.-R. Aerni, A. Gerritsen et al., “Comparing steroid estrogen, and nonylphenol content across a range of European sewage plants with different treatment and management practices,” Water Research, vol. 39, no. 1, pp. 47–58, 2005.
View at: Publisher Site | Google ScholarH. Andersen, H. Siegrist, B. Halling-Sørensen, and T. A. Ternes, “Fate of estrogens in a municipal sewage treatment plant,” Environmental Science and Technology, vol. 37, no. 18, pp. 4021–4026, 2003.
View at: Publisher Site | Google ScholarL. D. Nghiem, A. I. Schäfer, and T. D. Waite, “Adsorptive interactions between membranes and trace contaminants,” Desalination, vol. 147, no. 1–3, pp. 269–274, 2002.
View at: Publisher Site | Google ScholarM. M. Huber, T. A. Ternes, and U. von Gunten, “Removal of estrogenic activity and formation of oxidation products during ozonation of 17-ethinylestradiol,” Environmental Science and Technology, vol. 38, no. 19, pp. 5177–5186, 2004.
View at: Publisher Site | Google ScholarY. Ohko, K.-I. Iuchi, C. Niwa et al., “17-estradiol degradation by photocatalysis as a means of reducing estrogenic activity,” Environmental Science and Technology, vol. 36, no. 19, pp. 4175–4181, 2002.
View at: Publisher Site | Google ScholarH. Coleman, M. Abdullah, B. Eggins, and F. Palmer, “Photocatalytic degradation of 17-ostradiol, oestriol and 17-ethynyloestradiol in water monitored using fluorescence spectroscopy,” Applied Catalysis B: Environmental, vol. 55, no. 1, pp. 23–30, 2005.
View at: Publisher Site | Google ScholarT. Malygina, S. Preis, and J. Kallas, “The role of pH in aqueous photocatalytic oxidation of -estradiol,” International Journal of Photoenergy, vol. 7, no. 4, pp. 187–191, 2005.
View at: Publisher Site | Google ScholarA. L. Linsebigler, G. Lu, and J. T. Yates Jr., “Photocatalysis on surfaces: principles, mechanisms, and selected results,” Chemical Reviews, vol. 95, no. 3, pp. 735–758, 1995.
View at: Publisher Site | Google ScholarG. Boeije, R. Corstanje, A. Rottiers, and D. Schowanek, “Adaptation of the CAS test system and synthetic sewage for biological nutrient removal—part I: development of a new synthetic sewage,” Chemosphere, vol. 38, no. 4, pp. 699–709, 1999.
View at: Publisher Site | Google ScholarT. Karpova, A. L. Barros Torres, S. Preis, and J. Kallas, “Selective photocatalytic oxidation of steroid estrogens in the presence of saccharose and ethanol as co-pollutants,” to appear in Environmental Chemistry Letters.
View at: Google ScholarP. Mulvenna and G. Savidge, “A modified manual method for the determination of urea in seawater using diacetylmonoxime reagent,” Esturiane, Coastal and Shelf Science, vol. 34, no. 5, pp. 429–438, 1992.
View at: Publisher Site | Google ScholarL. Goeyens, N. Kindermans, M. Abu Yusuf, and M. Elskens, “A room temperature procedure for the manual determination of urea in seawater,” Estuarine, Coastal and Shelf Science, vol. 47, no. 4, pp. 415–418, 1998.
View at: Publisher Site | Google ScholarA. E. Greenberg, Ed., Standard Methods for the Examination of Water and Wastewater, American Public Health Association, Washington, DC, USA, 19th edition, 1995.