Research Article
Synthesis of Triphenyltin (IV) and Dibutyltin (IV) Complexes of 1-Aryl-2,5-dithiohydrazodicarbonamides and Their Characterization
Table 1
Analytical data and behavior of organotin (IV) dithiohydrazodicarbonamide complexes.
| | Complex empirical formula | Color | Anal. % | Found (calculated) | Molar conductance 10−3 M in DMSO (ohm−1 mol−1 cm2) | | C | H | N | S | Sn |
| Ph3Sn(Phthc)
C26H24N4S2Sn | Pale white | 54.73 (54.35) | 4.21 (4.18) | 9.82 (9.75) | 11.22 (11.14) | 20.70 (20.55) | 10.90 | Bu2Sn(Phthc)2
C24H36N8S4Sn | Pinkish white | 42.35 (42.22) | 5.29 (5.27) | 16.47 (16.42) | 18.82 (18.76) | 17.35 (17.30) | 15.50 | Ph3Sn(Bzthc)
C27H26N4S2Sn | White | 55.91 (55.10) | 4.40 (4.42) | 9.49 (9.52) | 10.84 (10.88) | 20.01 (20.06) | 9.63 | Bu2Sn(Bzthc)2Et
C26H40N8S4Sn | Dirty white | 44.08 (43.94) | 5.64 (5.63) | 15.81 (15.77) | 18.07 (18.02) | 16.66 (16.61) | 14.70 | Ph3Sn(EtOPhthc)
C28H28N4OS2Sn | Cream | 54.45 (54.19) | 4.86 (4.83) | 9.07 (9.03) | 10.37 (10.32) | 19.12 (19.03) | 6.15 | Bu2Sn(EtOPhthc)2
C28H44N8O2S4Sn | White | 43.86 (43.63) | 5.74 (5.71) | 14.62 (14.54) | 16.71 (16.62) | 15.40 (13.32) | 9.61 |
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